Detecting defects in tomorrow's technology: Study enhances understanding of likely candidate for next-generation chips – Phys.org


Forget Password?
Learn more
share this!
3
Twit
Share
Email
July 9, 2024
This article has been reviewed according to Science X’s editorial process and policies. Editors have highlighted the following attributes while ensuring the content’s credibility:
fact-checked
trusted source
proofread
by Rachel Kremen,
Silicon computer chips have served us well for more than half a century. The tiniest features on chips currently sold are approximately 3 nanometers—a startlingly small size given that a human hair is roughly 80,000 nanometers wide. Reducing the size of features on chips will help us meet our endless need for more memory and processing power in the palm of our hand. But the limit of what can be achieved with standard materials and processes is near.
Researchers at the U.S. Department of Energy’s (DOE) Princeton Plasma Physics Laboratory (PPPL) are applying their expertise in physics, chemistry and computer modeling to create the next generation of computer chips, aiming for processes and materials that will produce chips with smaller features.
“All of our existing electronic devices use chips made up of silicon, which is a three-dimensional material. Now, many companies are investing a lot in chips made up of two-dimensional materials,” said Shoaib Khalid, an associate research physicist at PPPL. The materials actually exist in three dimensions, but they are so thin—often made up of only a few layers of atoms—that scientists have taken to calling them 2D.
Khalid, together with PPPL’s Bharat Medasani and Anderson Janotti from the University of Delaware, investigated one potential silicon replacement: a 2D material known as a transition-metal dichalcogenide (TMD). Their paper, published in the journal 2D Materials, details the variations that can occur in the atomic structure of TMDs, why they happen and how they affect the material.
Information about these variations lays the groundwork for refining the processes needed to create next-generation computer chips. Ultimately, the goal is to design plasma-based manufacturing systems that can create TMD-based semiconductors made to the precise specifications required for the application.
A TMD can be as thin as three atoms high. Think of it like a tiny metal sandwich. The bread is made of a chalcogen element: oxygen, sulfur, selenium or tellurium. The filling is a layer of transition metal—any metal from groups 3 to 12 in the periodic table of elements.
A bulk TMD has five or more layers of atoms. The atoms are arranged in a crystal structure or lattice. Ideally, the atoms are organized in a precise and consistent pattern throughout the lattice.
In reality, small alterations can be found in the pattern. One spot in the pattern might be missing an atom, or an atom might be found in an odd location. Scientists call these alterations defects, but they can have a beneficial impact on the material.
Some TMD defects, for example, can make the semiconductor more electrically conductive. Good or bad, it is critical that scientists understand why defects happen and how they will affect the material so they can incorporate or eliminate these defects as necessary. Understanding common defects also allows the researchers to explain the results from past experiments with TMDs.
“When bulk TMDs are made, they have excess electrons,” Khalid said, adding that researchers were not sure why these excess negatively charged particles were present. “In this work, we explain that the excess electrons can be caused by hydrogen.”
The researchers came to this conclusion after calculating the amount of energy that would be required to form different kinds of TMD defects. They looked at defects involving chalcogen vacancies, which were previously known to be present in TMDs, and defects involving hydrogen because this element is often present during the manufacturing process.
Researchers are particularly interested in finding out which defects require minimal formation energy because these are the ones that are likely to occur—it doesn’t take much energy for them to happen.
The team then investigated the role of each of the low-formation-energy defects. Specifically, they wanted to know how each defect configuration might impact the electrical charge of the material.
The researchers found that one of the defect configurations involving hydrogen provides excess electrons, which creates negatively charged semiconductor material, known as an . Computer chips are made using combinations of n-type semiconductor material and positively charged, or p-type, material.
The other type of defect explored in the paper is known as a chalcogen vacancy: a missing atom of oxygen, sulfur, selenium or tellurium, depending on the type of TMD. The researchers focused on explaining the results of past experiments on flakes of the bulk TMD material molybdenum disulfide.
The experiments, which involved shining light on the TMD, showed unexpected frequencies of light coming from the TMD. These unexpected frequencies, the researchers found, could be explained by the movement of electrons related to the chalcogen vacancy.
“This is a common defect. They can often see it from the images of scanning tunneling microscopes when they grow the TMD film,” Khalid said. “Our work provides a strategy to investigate the presence of these vacancies in the bulk TMDs. We explained past experimental results shown in molybdenum disulfide, and then we predicted a similar thing for other TMDs.”
The process suggested by the researchers involves analyzing the TMD for defects using measurement techniques called photoluminescence to see which frequencies of light are emitted by the material. The peak frequency of light can be used to determine the electron configurations of the atoms in the TMD and the presence of chalcogen defects.
The journal article includes information about the frequencies that would be emitted by five types of TMDs with chalcogen vacancies, including molybdenum disulfide. The results, therefore, provide a guideline for investigating chalcogen vacancies in future experiments.
More information: Shoaib Khalid et al, Role of chalcogen vacancies and hydrogen in the optical and electrical properties of bulk transition-metal dichalcogenides, 2D Materials (2024). DOI: 10.1088/2053-1583/ad4720
Provided by Princeton Plasma Physics Laboratory
Explore further
Facebook
Twitter
Email
Feedback to editors
16 hours ago
0
16 hours ago
0
18 hours ago
0
19 hours ago
0
20 hours ago
0
2 hours ago
3 hours ago
3 hours ago
7 hours ago
7 hours ago
10 hours ago
10 hours ago
10 hours ago
10 hours ago
10 hours ago
16 hours ago
19 hours ago
Jul 6, 2024
Jul 4, 2024
Jul 3, 2024
Jul 2, 2024
More from Atomic and Condensed Matter
Apr 11, 2024
Apr 18, 2023
Apr 19, 2021
Jun 19, 2024
May 2, 2024
Apr 19, 2018
10 hours ago
14 hours ago
16 hours ago
Jul 6, 2024
Jul 5, 2024
Jul 5, 2024
Use this form if you have come across a typo, inaccuracy or would like to send an edit request for the content on this page. For general inquiries, please use our contact form. For general feedback, use the public comments section below (please adhere to guidelines).
Please select the most appropriate category to facilitate processing of your request
Thank you for taking time to provide your feedback to the editors.
Your feedback is important to us. However, we do not guarantee individual replies due to the high volume of messages.
Your email address is used only to let the recipient know who sent the email. Neither your address nor the recipient’s address will be used for any other purpose. The information you enter will appear in your e-mail message and is not retained by Phys.org in any form.

Get weekly and/or daily updates delivered to your inbox. You can unsubscribe at any time and we’ll never share your details to third parties.
More information Privacy policy
We keep our content available to everyone. Consider supporting Science X’s mission by getting a premium account.
Medical research advances and health news
The latest engineering, electronics and technology advances
The most comprehensive sci-tech news coverage on the web

source

Oh hi there 👋
It’s nice to meet you.

Sign up to receive awesome content in your inbox, every month.

We don’t spam! Read our privacy policy for more info.

Leave a Reply

Your email address will not be published. Required fields are marked *